Higher alcohol 1-octanol was evaluated as jet fuel potential. The synthesis of the 1-octanol was modeled and the technological, economic and environmental evaluation of the global production process of the rice husk gasification was performed. The best operating conditions to 1-octanol synthesis were obtained in packed bed reactor PBR using Matlab software. Mass and energy balances were calculated using Aspen Plus Software. Economic assessment was developed using Aspen Process Economic Analyzer Software. Environmental impact evaluation was carried out using the waste reduction algorithm WAR. Process yield was 0.83 kg of 1-Octanol by kg of rice husk. Total production cost obtained was USD 0.957 per kg of 1-octanol and the total PEI of product leave the system is 0.08142 PEI/kg with a PEI mitigated of 12.97 PEI/kg. Production process of high alcohols from rice husk shows a high potential technological, economical and environmental as a sustainable industry at take advantage of an agroindustrial residue and transformed in products with added value and energy. 1-octanol as jet fuel has a potential but need to be more studied for direct use in jet motors.Higher alcohol 1-octanol was evaluated as jet fuel potential. The synthesis of the 1-octanol was modeled and the technological, economic and environmental evaluation of the global production process of the rice husk gasification was performed. The best operating conditions to 1-octanol synthesis were obtained in packed bed reactor PBR using Matlab software. Mass and energy balances were calculated using Aspen Plus Software. Economic assessment was developed using Aspen Process Economic Analyzer Software. Environmental impact evaluation was carried out using the waste reduction algorithm WAR. Process yield was 0.83 kg of 1-Octanol by kg of rice husk. Total production cost obtained was USD 0.957 per kg of 1-octanol and the total PEI of product leave the system is 0.08142 PEI/kg with a PEI mitigated of 12.97 PEI/kg. Production process of high alcohols from rice husk shows a high potential technological, economical and environmental as a sustainable industry at take advantage of an agroindustrial residue and transformed in products with added value and energy. 1-octanol as jet fuel has a potential but need to be more studied for direct use in jet motors.